3-[(E)-(4-Chlorobenzylidene)amino]-1-phenylthiourea

3-[(E)-(4-Chlorobenzylidene)amino]-1-phenylthiourea

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In the title compound, C14H12ClN3S, the dihedral angle between the terminal benzene rings is 56.6 (2)°; the benzene rings lie to the same side of the molecule.The major twist in the molecule Toys occurs around the Car—N bond (ar is aromatic) [C—N—C—C = 49.9 (5)°].The configuration about the N=C bond Makeup Bags [1.

271 (4) Å] is E.The amine H atoms lie on opposite sides of the molecule with one forming an intramolecular N—H.N(imine) hydrogen bond and an S(5) ring.In the crystal, centrosymmetric dimers are formed via {.HNC=S}2 synthons.